Mechanistic insight into proton-coupled mixed valency

Wilkinson, Luke A., Vincent, Kevin B., Meijer, Anthony J. H. M. and Patmore, Nathan J. (2016) Mechanistic insight into proton-coupled mixed valency. Chemical Communications, 52 (1). pp. 100-103. ISSN 1359-7345

Abstract

Stabilisation of the mixed-valence state in [Mo2(TiPB)3(HDOP)]2+ (HTiPB = 2,4,6-triisopropylbenzoic acid, H2DOP = 3,6-dihydroxypyridazine) by electron transfer (ET) is related to the proton coordinate of the bridging ligands. Spectroelectrochemical studies suggest that ET is slower than 109 s−1. The mechanism has been probed using DFT calculations, which show that proton transfer induces a larger dipole in the molecule resulting in ET.

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Title:

Mechanistic insight into proton-coupled mixed valency

Creators:

Wilkinson, Luke A., Vincent, Kevin B., Meijer, Anthony J. H. M. and Patmore, Nathan J.

Identification Number:

10.1039/C5CC07101A

Official URL:

http://dx.doi.org/10.1039/C5CC07101A

Date:

1 January 2016

Subjects:

Q Science > QD Chemistry

Schools:

School of Applied Sciences

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Article

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Date Deposited:

27 Apr 2016 10:16

Revision:

17

Last Modified:

28 Aug 2021 17:13

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