Cantrill, Alexander, Jarvis, Ashley, Osborn, Helen, Ouadi, Ali and Sweeney, Joseph B. (1996) Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines. Synlett, 9. pp. 847-849. ISSN 0936-5214
Abstract

N-Diphenylphosphinyl-3-ethenyl-2-phenylaziridine (1) and N-diphenylphosphinyl-3-ethenyl-2-(4-bromophenyl)aziridine (2) are prepared by reaction of α-bromo allyllithium with N-diphenylphosphinyl aldimines in the presence of zinc chloride. (1) and (2) undergo efficient SN2' ring-opening reaction with several nucleophiles.

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