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Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines

Cantrill, Alexander, Jarvis, Ashley, Osborn, Helen, Ouadi, Ali and Sweeney, Joseph B. (1996) Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines. Synlett, 9. pp. 847-849. ISSN 0936-5214
Abstract

N-Diphenylphosphinyl-3-ethenyl-2-phenylaziridine (1) and N-diphenylphosphinyl-3-ethenyl-2-(4-bromophenyl)aziridine (2) are prepared by reaction of α-bromo allyllithium with N-diphenylphosphinyl aldimines in the presence of zinc chloride. (1) and (2) undergo efficient SN2' ring-opening reaction with several nucleophiles.

Information
URI:
https://eprints.hud.ac.uk/id/eprint/15397
URI:
https://eprints.hud.ac.uk/id/eprint/15397
URI:
https://eprints.hud.ac.uk/id/eprint/15397
URI:
https://eprints.hud.ac.uk/id/eprint/15397
Title:
Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines
Creators:
Cantrill, Alexander, Jarvis, Ashley, Osborn, Helen, Ouadi, Ali and Sweeney, Joseph B.
Identification Number:
10.1055/s-1996-5605
Official URL:
http://dx.doi.org/10.1055/s-1996-5605
Date:
September 1996
Subjects:
Q Science > QD Chemistry
Schools:
School of Applied Sciences
Library
Item Type:
Article
Depositing User:
Joseph Sweeney
Date Deposited:
17 Oct 2012 12:57
Revision:
9
Last Modified:
28 Aug 2021 11:22
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