Chiral Aryl Iodide-Catalyzed Enantioselective α-Oxidation of Ketones

Rodríguez, Arantxa; Moran, Wesley J.

Chiral Aryl Iodide-Catalyzed Enantioselective α-Oxidation of Ketones

Rodríguez, Arantxa and Moran, Wesley J. (2012) Chiral Aryl Iodide-Catalyzed Enantioselective α-Oxidation of Ketones. Synthesis, 44 (8). pp. 1178-1182. ISSN 00397881

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Abstract

Several chiral aryl iodides were synthesized and assessed as catalysts in the enantioselective α-oxytosylation of propiophenone and the oxidative cyclization of 5-oxo-5-phenylpentanoic acid to 5-benzoyldihydrofuran-2(3H)-one. The highest enantioselectivities obtained were 18 and 51% ee, respectively. The latter is the highest selectivity recorded to date for this reaction.

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URI:

https://eprints.hud.ac.uk/id/eprint/13308

Title:

Chiral Aryl Iodide-Catalyzed Enantioselective α-Oxidation of Ketones

Creators:

Rodríguez, Arantxa and Moran, Wesley J.

Identification Number:

10.1055/s-0031-1290590

Official URL:

http://dx.doi.org/10.1055/s-0031-1290590

Date: