Wilkinson, Luke A., Vincent, Kevin B., Meijer, Anthony J. H. M. and Patmore, Nathan J. (2016) Mechanistic insight into proton-coupled mixed valency. Chemical Communications, 52 (1). pp. 100-103. ISSN 1359-7345
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Abstract
Stabilisation of the mixed-valence state in [Mo2(TiPB)3(HDOP)]2+ (HTiPB = 2,4,6-triisopropylbenzoic acid, H2DOP = 3,6-dihydroxypyridazine) by electron transfer (ET) is related to the proton coordinate of the bridging ligands. Spectroelectrochemical studies suggest that ET is slower than 109 s−1. The mechanism has been probed using DFT calculations, which show that proton transfer induces a larger dipole in the molecule resulting in ET.
Item Type: | Article |
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Subjects: | Q Science > QD Chemistry |
Schools: | School of Applied Sciences |
Related URLs: | |
Depositing User: | Nathan Patmore |
Date Deposited: | 27 Apr 2016 10:16 |
Last Modified: | 28 Aug 2021 17:13 |
URI: | http://eprints.hud.ac.uk/id/eprint/28150 |
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