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Intra-and inter-molecular general base catalysis in the aminolysis of benzylpenicillin

Martin, Anthony F., Morris, Jeffrey J. and Page, Michael I. (1976) Intra-and inter-molecular general base catalysis in the aminolysis of benzylpenicillin. Chemical Communications (13). pp. 495-496. ISSN 1359-7345
Abstract

The rate law for the aminolysis of benzylpenicillin is obtained and Brønsted -values indicate that the general-base-catalysed reaction occurs with a stepwise proton-transfer step; intramolecular general base catalysis occurs in the reaction of ethylenediamine with penicillin.

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Item Type:
Article
Depositing User:
Sharon Beastall
Date Deposited:
11 Nov 2009 13:15
Revision:
11
Last Modified:
28 Aug 2021 10:52
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