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Equilibria between enamine and B-unsaturated imine in cephalosporin hydrolysis

Buckwell, Stephen C., Page, Michael I. and Longridge, Jethro L. (1986) Equilibria between enamine and B-unsaturated imine in cephalosporin hydrolysis. Chemical Communications (13). pp. 1039-1040. ISSN 1359-7345
Abstract

The normal product of hydrolysis of cephalosporins with a leaving group at C-3 is an ,-unsaturated imine which is demonstrated to be in equilibrium with its precursor, an enamine; the equilibrium constants for this process are reported for thiolate anions which generate a Bronsted lg of 0.71

Information
URI:
https://eprints.hud.ac.uk/id/eprint/6171
URI:
https://eprints.hud.ac.uk/id/eprint/6171
URI:
https://eprints.hud.ac.uk/id/eprint/6171
URI:
https://eprints.hud.ac.uk/id/eprint/6171
URI:
https://eprints.hud.ac.uk/id/eprint/6171
Title:
Equilibria between enamine and B-unsaturated imine in cephalosporin hydrolysis
Creators:
Buckwell, Stephen C., Page, Michael I. and Longridge, Jethro L.
Identification Number:
10.1039/C39860001039
Official URL:
http://dx.doi.org/10.1039/C39860001039
Date:
July 1986
Subjects:
Q Science > Q Science (General)
Q Science > QD Chemistry
Schools:
School of Applied Sciences
Library
Item Type:
Article
Depositing User:
Sharon Beastall
Date Deposited:
11 Nov 2009 12:25
Revision:
11
Last Modified:
28 Aug 2021 10:52
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