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Evidence for the formation of isothiocyanate during sulphurisation of triphenyl phosphines using xanthane hydride

Hanusek, Jifi, Russell, Mark A., Laws, Andrew P. and Page, Michael I. (2007) Evidence for the formation of isothiocyanate during sulphurisation of triphenyl phosphines using xanthane hydride. Tetrahedron Letters, 48 (3). pp. 417-419. ISSN 0040-4039
Abstract

Contrary to a previous report, the sulfurisation of triphenylphosphines and trialkyl phosphites by 3-amino-1,2,4-dithiazole-5-thione (xanthane hydride) does not yield carbon disulfide and cyanamide as the additional reaction products but unstable thiocarbamoyl isothiocyanate which has been trapped with nucleophiles.

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https://eprints.hud.ac.uk/id/eprint/506
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https://eprints.hud.ac.uk/id/eprint/506
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https://eprints.hud.ac.uk/id/eprint/506
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https://eprints.hud.ac.uk/id/eprint/506
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https://eprints.hud.ac.uk/id/eprint/506
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https://eprints.hud.ac.uk/id/eprint/506
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https://eprints.hud.ac.uk/id/eprint/506
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https://eprints.hud.ac.uk/id/eprint/506
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https://eprints.hud.ac.uk/id/eprint/506
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https://eprints.hud.ac.uk/id/eprint/506
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https://eprints.hud.ac.uk/id/eprint/506
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https://eprints.hud.ac.uk/id/eprint/506
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https://eprints.hud.ac.uk/id/eprint/506
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https://eprints.hud.ac.uk/id/eprint/506
URI:
https://eprints.hud.ac.uk/id/eprint/506
URI:
https://eprints.hud.ac.uk/id/eprint/506
URI:
https://eprints.hud.ac.uk/id/eprint/506
URI:
https://eprints.hud.ac.uk/id/eprint/506
URI:
https://eprints.hud.ac.uk/id/eprint/506
URI:
https://eprints.hud.ac.uk/id/eprint/506
URI:
https://eprints.hud.ac.uk/id/eprint/506
Title:
Evidence for the formation of isothiocyanate during sulphurisation of triphenyl phosphines using xanthane hydride
Creators:
Hanusek, Jifi, Russell, Mark A., Laws, Andrew P. and Page, Michael I.
Identification Number:
10.1016/j.tetlet.2006.11.075
Official URL:
http://dx.doi.org/10.1016/j.tetlet.2006.11.075
Date:
January 2007
Subjects:
Q Science > Q Science (General)
Q Science > QD Chemistry
Schools:
School of Applied Sciences
School of Applied Sciences > Biomolecular Sciences Research Centre
Additional Information:
UoA 18 (Chemistry)
Library
Item Type:
Article
Depositing User:
Sara Taylor
Date Deposited:
04 Feb 2008 10:37
Revision:
13
Last Modified:
28 Aug 2021 10:38
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