Efficient electrophilic catalysis of 1,5-anhydrocellobiitol hydrolysis by Al(III); implications for the conservation of “rosin-alum” sized paper

Baty, John and Sinnott, Michael L. (2004) Efficient electrophilic catalysis of 1,5-anhydrocellobiitol hydrolysis by Al(III); implications for the conservation of “rosin-alum” sized paper. Chemical Communications. pp. 866-867. ISSN 1364-548X

Abstract

Added Al2SO4 greatly accelerates the hydrolysis at 150.0 °C of 1,5-anhydrocellobiitol, a model for the (14) linkages in cellulose, in succinate buffers of room temperature pH 3.05 and 3.35; Ea values for 20 mM AlIII- and H+-catalysed hydrolyses are 109 ± 3 and 140 ± 1 kJ mol–1, respectively.

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Title:

Efficient electrophilic catalysis of 1,5-anhydrocellobiitol hydrolysis by Al(III); implications for the conservation of “rosin-alum” sized paper

Creators:

Baty, John and Sinnott, Michael L.

Identification Number:

10.1039/b316417a

Official URL:

http://dx.doi.org/10.1039/b316417a

Date:

2004

Subjects:

Q Science > QD Chemistry

Schools:

School of Applied Sciences
School of Applied Sciences > Biomolecular Sciences Research Centre

Additional Information:

UoA 18 (Chemistry) This journal is © The Royal Society of Chemistry 2004

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Item Type:

Article

Depositing User:

Date Deposited:

13 Jul 2007

Revision:

18

Last Modified:

28 Aug 2021 23:33

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