Skip to main content

A one-pot synthesis of α-formyl-α-allylacetates via nucleophilic catalysis.

Chung, William, Lindovska, Petra and Camp, Jason (2011) A one-pot synthesis of α-formyl-α-allylacetates via nucleophilic catalysis. Tetrahedron Letters, 52 (50). pp. 6785-6787. ISSN 0040-4039
Abstract

A step-economical one-pot nucleophilic catalysis/thermal Claisen rearrangement protocol for the direct synthesis of α-formyl-α-allylacetates from allylic alcs. and activated alkynes has been developed. The product α-formyl-α-allylacetates were further reacted in situ to give either protected enol ethers or β-hydroxy-4-pentenoates. [on SciFinder(R)]

Information
URI:
https://eprints.hud.ac.uk/id/eprint/22274
URI:
https://eprints.hud.ac.uk/id/eprint/22274
Title:
A one-pot synthesis of α-formyl-α-allylacetates via nucleophilic catalysis.
Creators:
Chung, William, Lindovska, Petra and Camp, Jason
Identification Number:
https://doi.org/10.1016/j.tetlet.2011.10.035
Official URL:
http://dx.doi.org/10.1016/j.tetlet.2011.10.035
Date:
December 2011
Subjects:
Q Science > Q Science (General)
Q Science > QD Chemistry
Schools:
School of Applied Sciences
Additional Information:
Unmapped bibliographic data: PY - 2011/// [EPrints field already has value set] M3 - 10.1016/j.tetlet.2011.10.035 [Field not mapped to EPrints] JA - Tetrahedron Lett. [Field not mapped to EPrints]
Uncontrolled Keywords:
allylic alc activated alkyne nucleophilic catalysis addn Claisen rearrangement, formyl allylacetate prepn protection redn
Library
Item Type:
Article
Depositing User:
Sara Taylor
Date Deposited:
13 Nov 2014 16:33
Revision:
9
Last Modified:
28 Aug 2021 11:43
Statistics
CORE (COnnecting REpositories)
Tools
Add to AnyAdd to TwitterAdd to FacebookAdd to LinkedinAdd to PinterestAdd to Email