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Determination of the temperature and enthalpy of the solid-solid phase transition of caesium nitrate by differential scanning calorimetry

Charrier, E., Charsley, Edward L., Markham, H.M., Berger, B. and Griffiths, Trevor T. (2006) Determination of the temperature and enthalpy of the solid-solid phase transition of caesium nitrate by differential scanning calorimetry. Thermochimica Acta, 445. pp. 36-39. ISSN 0040-6031
Abstract

The equilibrium temperature of the solid–solid phase transition of high purity caesium nitrate has been measured accurately by stepwise heating and by the extrapolation to zero heating rate method. A mean value of 154.3 ± 0.1 °C was obtained using two different heat flux DSC instruments. A value of 3.44 ± 0.04 kJ mol−1 was determined for the enthalpy of transition.

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Depositing User:
Briony Heyhoe
Date Deposited:
12 Jul 2007
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28 Aug 2021 23:35
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