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Relationship between metal–metal bond length and internal rotation in diruthenium tetracarboxylate paddlewheel complexes

Gracia, Raquel, Adams, Harry and Patmore, Nathan J. (2009) Relationship between metal–metal bond length and internal rotation in diruthenium tetracarboxylate paddlewheel complexes. Dalton Transactions (2). pp. 259-261. ISSN 1477-9226
Abstract

The Ru–Ru bond length for Ru2II,III and Ru2II,II paddlewheel complexes containing the bulky carboxylate ligand 2,4,6-triisopropylbenzoate was found to decrease despite a reduction in Ru–Ru bond order, due to increased internal rotation.

Information
URI:
https://eprints.hud.ac.uk/id/eprint/18787
URI:
https://eprints.hud.ac.uk/id/eprint/18787
URI:
https://eprints.hud.ac.uk/id/eprint/18787
URI:
https://eprints.hud.ac.uk/id/eprint/18787
Title:
Relationship between metal–metal bond length and internal rotation in diruthenium tetracarboxylate paddlewheel complexes
Creators:
Gracia, Raquel, Adams, Harry and Patmore, Nathan J.
Identification Number:
10.1039/B820287G
Official URL:
http://dx.doi.org/10.1039/B820287G
Date:
14 January 2009
Subjects:
Q Science > Q Science (General)
Q Science > QD Chemistry
Schools:
School of Applied Sciences
Library
Item Type:
Article
Depositing User:
Sara Taylor
Date Deposited:
03 Oct 2013 09:46
Revision:
17
Last Modified:
28 Aug 2021 19:38
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