Oxidative Rearrangement of Tertiary Propargylic Alcohols

Rodríguez, Arantxa and Moran, Wesley J. (2013) Oxidative Rearrangement of Tertiary Propargylic Alcohols. Synlett, 24 (1). pp. 102-104. ISSN 0936-5214

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Abstract

An oxidative rearrangement of tertiary alcohols mediated by m-CPBA is described that generates tetrasubstituted alkenes with a carboxylic acid substituent. The mechanism of the reaction is proposed to proceed through epoxidation of the alkyne to form an oxirene that undergoes a 1,2-aryl shift.

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URI:

https://eprints.hud.ac.uk/id/eprint/16215

URI:

https://eprints.hud.ac.uk/id/eprint/16215

URI:

https://eprints.hud.ac.uk/id/eprint/16215

URI:

https://eprints.hud.ac.uk/id/eprint/16215

URI:

https://eprints.hud.ac.uk/id/eprint/16215

URI:

https://eprints.hud.ac.uk/id/eprint/16215

URI:

https://eprints.hud.ac.uk/id/eprint/16215

URI:

https://eprints.hud.ac.uk/id/eprint/16215

URI:

https://eprints.hud.ac.uk/id/eprint/16215

URI:

https://eprints.hud.ac.uk/id/eprint/16215

URI:

https://eprints.hud.ac.uk/id/eprint/16215

URI:

https://eprints.hud.ac.uk/id/eprint/16215

URI:

https://eprints.hud.ac.uk/id/eprint/16215

URI:

https://eprints.hud.ac.uk/id/eprint/16215

Title:

Oxidative Rearrangement of Tertiary Propargylic Alcohols

Creators:

Rodríguez, Arantxa and Moran, Wesley J.

Identification Number:

10.1055/s-0032-1317711

Official URL:

http://dx.doi.org/10.1055/s-0032-1317711

Date:

January 2013

Subjects:

Q Science > QD Chemistry

Schools:

School of Applied Sciences

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Article

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Date Deposited:

06 Dec 2012 15:38

Revision:

13

Last Modified:

28 Aug 2021 11:24

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