Dillon, Michael P., Simpson, Thomas J. and Sweeney, Joseph B. (1992) Enantioselective synthesis of monocerin and fusarentin ethers: Antifungal and insecticidal fungal metabolites. Tetrahedron Letters, 33 (49). pp. 7569-7572. ISSN 0040-4039
Abstract

Fusarentin 4,5-dimethyl ether (4) is synthesized via condensation of the benzylic anion of ethyl 3,4,5-trimethoxy-6-methylbenzoate (7) with (S)-3-tetrahydropyranyloxyhexanal (8); subsequent biomimetic cyclisation of (4) gives monocerin (1).

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