Diastereospecific hydroxyselenation of cyclohex-2-enyl phenylglycinates

Haughan, Alan F. and Sweeney, Joseph B. (1994) Diastereospecific hydroxyselenation of cyclohex-2-enyl phenylglycinates. Tetrahedron: Asymmetry, 5 (2). pp. 177-180. ISSN 0957-4166

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Abstract

Cyclohex-2-enyl esters of homochiral (R)-Z-phenylglycine undergo completely regio- and diastereospecific addition reactions with N-phenylselenophthalimide. The resulting selenoalcohols are separable by routine chromatography and may be converted into homochiral 1,3-cyclohexonediols in which the hydroxyl groups are differentiated.

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URI:

https://eprints.hud.ac.uk/id/eprint/15412

Title:

Diastereospecific hydroxyselenation of cyclohex-2-enyl phenylglycinates

Creators:

Haughan, Alan F. and Sweeney, Joseph B.

Identification Number:

10.1016/S0957-4166(00)86166-2

Official URL:

http://dx.doi.org/10.1016/S0957-4166(00)86166-2

Date: