Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids

Bullock, Sam, Hallett, Andrew J., Harding, Lindsay P., Higginson, Joshua J., Piela, Sean A.F., Pope, Simon J.A. and Rice, Craig R. (2012) Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids. Dalton Transactions. ISSN 14779226

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Abstract

A new route to luminescent derivatives of androgenic steroids containing a ketone group in the 3-
or 17-position has been developed. Reaction with the fac-Re(CO)3Cl complex of 3,3’-diamino-2,2’-
bipyridine (complex 1) afforded a cyclic aminal product with different steroids. The rate of reaction
and yield varies according to the conjugation or steric hindrance around the ketone group

Information

URI:

https://eprints.hud.ac.uk/id/eprint/15205

URI:

https://eprints.hud.ac.uk/id/eprint/15205

Title:

Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids

Creators:

Bullock, Sam, Hallett, Andrew J., Harding, Lindsay P., Higginson, Joshua J., Piela, Sean A.F., Pope, Simon J.A. and Rice, Craig R.

Identification Number:

10.1039/C2DT31476B

Official URL: