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Structural studies of a novel heterocyclic phosphorane

Gabbutt, Christopher D., Hepworth, John D., Heron, B. Mark, Jones, Alan M., Raper, Eric S. and Clegg, William (1998) Structural studies of a novel heterocyclic phosphorane. Phosphorus, Sulfur, and Silicon and the Related Elements, 143 (1). pp. 221-230. ISSN 1042-6507
Abstract

Reaction of 2,2,6-trimethylthiochroman-3,4-dione with an excess of methylenetriphenylphosphorane yields the stabilised ylide (4) by way of an α-ketol rearrangement. X-Ray crystallography indicates that (4) exists as the (a-isomer and provides supporting evidence for an enolate structure.

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Title:
Structural studies of a novel heterocyclic phosphorane
Creators:
Gabbutt, Christopher D., Hepworth, John D., Heron, B. Mark, Jones, Alan M., Raper, Eric S. and Clegg, William
Identification Number:
10.1080/10426509808045499
Official URL:
http://dx.doi.org/10.1080/10426509808045499
Date:
November 1998
Subjects:
Q Science > Q Science (General)
Q Science > QD Chemistry
Schools:
School of Applied Sciences
Library
Item Type:
Article
Depositing User:
Sharon Beastall
Date Deposited:
20 Sep 2012 12:45
Revision:
13
Last Modified:
28 Aug 2021 11:21
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