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The oxidative ring expansion of spiro-annulated chroman-4-ones: Syntheses of the rotenoid core and related benzoxanthones

Gabbutt, Christopher D., Hepworth, John D., Heron, B. Mark and Thomas, Jean-Luc (1998) The oxidative ring expansion of spiro-annulated chroman-4-ones: Syntheses of the rotenoid core and related benzoxanthones. Tetrahedron Letters, 39 (8). pp. 881-884. ISSN 0040-4039
Abstract

Syntheses of dehydrorotenoid and benzoxanthone units from 2′-hydroxyacetophenone are described which feature a novel migration of spiro-substituted chroman-4-ones during their oxidative ring expansion. Conjugate reduction affords a trans B/C fused rotenoid and the related cis and trans fused tetrahydrobenzoxanthones

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https://eprints.hud.ac.uk/id/eprint/14993
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https://eprints.hud.ac.uk/id/eprint/14993
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https://eprints.hud.ac.uk/id/eprint/14993
Title:
The oxidative ring expansion of spiro-annulated chroman-4-ones: Syntheses of the rotenoid core and related benzoxanthones
Creators:
Gabbutt, Christopher D., Hepworth, John D., Heron, B. Mark and Thomas, Jean-Luc
Identification Number:
10.1016/S0040-4039(97)10646-3
Official URL:
http://dx.doi.org/10.1016/S0040-4039(97)10646-3
Date:
February 1998
Subjects:
Q Science > Q Science (General)
Q Science > QD Chemistry
Schools:
School of Applied Sciences
Library
Item Type:
Article
Depositing User:
Sharon Beastall
Date Deposited:
20 Sep 2012 12:23
Revision:
13
Last Modified:
28 Aug 2021 11:21
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