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Simultaneous Rheology and Small-Angle Scattering Experiments on Block Copolymer Gels and Melts in Cubic Phases

Hamley, Ian W., Pople, J.A., Gleeson, A. J., Komanschek, Bernd U. and Towns-Andrews, Elizabeth (1998) Simultaneous Rheology and Small-Angle Scattering Experiments on Block Copolymer Gels and Melts in Cubic Phases. Journal of Applied Crystallography, 31 (6). pp. 881-889. ISSN 0021-8898

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A new instrument for simultaneous small-angle X-ray scattering and rheology experiments on soft solids is described. This device is based on a commercial rheometer with a shear sandwich geometry in which the sample is subjected to a planar oscillatory deformation. This instrument has been used for time-resolved small-angle X-ray scattering/rheology experiments at the Synchrotron Radiation Source, Daresbury Laboratory, England. The focus has been in particular on the effect of large-amplitude shearing on the orientation of cubic phases in gels of block copolymers formed in concentrated solutions, and on the bicontinuous cubic phase of a block copolymer melt. Representative results are presented for face-centred cubic (f.c.c.) and bodycentred cubic (b.c.c.) phases in gels of poly(oxyethylene) ±poly(oxybutylene) diblock copolymers, and for the bicontinuous cubic `gyroid' structure in a poly- (ethylene-alt-propylene)±poly(dimethylsiloxane) diblock copolymer melt. The orientations of the micellar b.c.c. phases in the gels and the gyroid structure (belonging to the b.c.c. space group Ia3d) following large-amplitude shearing are shown to be the same, i.e. directionally oriented crystals are produced in both cases, in which (111) directions are oriented along the shear direction.

Item Type: Article
Subjects: T Technology > T Technology (General)
Q Science > Q Science (General)
Schools: Research and Enterprise Directorate
Depositing User: Cherry Edmunds
Date Deposited: 19 Jul 2010 15:34
Last Modified: 28 Aug 2021 10:58


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