Baxter, Nicholas J. and Page, Michael I. (1997) Evidence for a trigonal bipyramidal intermediate during nucleophilic substitution at a sulfonyl centre and for a sulfonylium cation in the acid catalysed reaction. Chemical Communications (21). pp. 2037-2038. ISSN 1359-7345
Metadata only available from this repository.Abstract
The rate of alkaline hydrolysis of a substituted -sultam shows a dominant term second-order in hydroxide ion, clearly indicating the reversible formation of a monoanionic trigonal bipyramidal intermediate; substituent effects and kinetic parameters for the acid catalysed hydrolysis are indicative of the formation of a sulfonylium ion intermediate.
Item Type: | Article |
---|---|
Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
Schools: | School of Applied Sciences |
Related URLs: | |
Depositing User: | Sharon Beastall |
Date Deposited: | 05 Nov 2009 11:57 |
Last Modified: | 28 Aug 2021 10:52 |
URI: | http://eprints.hud.ac.uk/id/eprint/6092 |
Downloads
Downloads per month over past year
Repository Staff Only: item control page
![]() |
View Item |