Evidence for the formation of isothiocyanate during sulphurisation of triphenyl phosphines using xanthane hydride

Hanusek, Jifi, Russell, Mark A., Laws, Andrew P. and Page, Michael I. (2007) Evidence for the formation of isothiocyanate during sulphurisation of triphenyl phosphines using xanthane hydride. Tetrahedron Letters, 48 (3). pp. 417-419. ISSN 0040-4039

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Abstract

Contrary to a previous report, the sulfurisation of triphenylphosphines and trialkyl phosphites by 3-amino-1,2,4-dithiazole-5-thione (xanthane hydride) does not yield carbon disulfide and cyanamide as the additional reaction products but unstable thiocarbamoyl isothiocyanate which has been trapped with nucleophiles.

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URI:

https://eprints.hud.ac.uk/id/eprint/506

Title:

Evidence for the formation of isothiocyanate during sulphurisation of triphenyl phosphines using xanthane hydride

Creators:

Hanusek, Jifi, Russell, Mark A., Laws, Andrew P. and Page, Michael I.

Identification Number:

https://doi.org/10.1016/j.tetlet.2006.11.075

Official URL:

http://dx.doi.org/10.1016/j.tetlet.2006.11.075

Date: