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Optically generated hyperpolarization for sensitivity enhancement in solution-state NMR spectroscopy

Dale, Matthew W. and Wedge, Christopher J. (2016) Optically generated hyperpolarization for sensitivity enhancement in solution-state NMR spectroscopy. Chemical Communications, 52 (90). pp. 13221-13224. ISSN 1359-7345

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Abstract

We show that optical excitation of radical triplet pair systems can produce a fourfold NMR signal enhancement in solution, without the need for microwave pumping. Development of optical hyperpolarization methods will significantly impact all NMR user groups by boosting sensitivity and reducing signal averaging times

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Item Type: Article
Uncontrolled Keywords: Nuclear magnetic resonance spectroscopy, Chemistry, Dynamic Nuclear Polarization
Subjects: Q Science > QC Physics
Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Christopher Wedge
Date Deposited: 13 Dec 2016 16:37
Last Modified: 12 Dec 2017 18:39
URI: http://eprints.hud.ac.uk/id/eprint/30367

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