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Optically generated hyperpolarization for sensitivity enhancement in solution-state NMR spectroscopy

Dale, Matthew W. and Wedge, Christopher J. (2016) Optically generated hyperpolarization for sensitivity enhancement in solution-state NMR spectroscopy. Chemical Communications, 52 (90). pp. 13221-13224. ISSN 1359-7345
Abstract

We show that optical excitation of radical triplet pair systems can produce a fourfold NMR signal enhancement in solution, without the need for microwave pumping. Development of optical hyperpolarization methods will significantly impact all NMR user groups by boosting sensitivity and reducing signal averaging times

Information
URI:
https://eprints.hud.ac.uk/id/eprint/30367
URI:
https://eprints.hud.ac.uk/id/eprint/30367
URI:
https://eprints.hud.ac.uk/id/eprint/30367
URI:
https://eprints.hud.ac.uk/id/eprint/30367
URI:
https://eprints.hud.ac.uk/id/eprint/30367
URI:
https://eprints.hud.ac.uk/id/eprint/30367
URI:
https://eprints.hud.ac.uk/id/eprint/30367
URI:
https://eprints.hud.ac.uk/id/eprint/30367
URI:
https://eprints.hud.ac.uk/id/eprint/30367
URI:
https://eprints.hud.ac.uk/id/eprint/30367
URI:
https://eprints.hud.ac.uk/id/eprint/30367
URI:
https://eprints.hud.ac.uk/id/eprint/30367
URI:
https://eprints.hud.ac.uk/id/eprint/30367
Title:
Optically generated hyperpolarization for sensitivity enhancement in solution-state NMR spectroscopy
Creators:
Dale, Matthew W. and Wedge, Christopher J.
Identification Number:
10.1039/C6CC06651H
Official URL:
http://dx.doi.org/10.1039/C6CC06651H
Date:
30 September 2016
Subjects:
Q Science > QC Physics
Q Science > QD Chemistry
Schools:
School of Applied Sciences
Uncontrolled Keywords:
Nuclear magnetic resonance spectroscopy, Chemistry, Dynamic Nuclear Polarization
Library
Item Type:
Article
Depositing User:
Christopher Wedge
Date Deposited:
13 Dec 2016 16:37
Revision:
204
Last Modified:
28 Aug 2021 16:30
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