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Rodríguez, Arantxa and Moran, Wesley J. (2016) Preparation of Alkyl Alkynyl Sulfones and Cyclic Vinyl Sulfones from Alkynyl(aryl)iodonium Salts. The Journal of Organic Chemistry, 81 (6). pp. 2543-2548. ISSN 0022-3263
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Official URL: http://dx.doi.org/10.1021/acs.joc.6b00124
Abstract
The reaction of alkyl sulfinates with alkynyl(aryl)iodonium salts provides a facile access in to otherwise difficult to obtain alkyl alkynyl sulfones and cyclic vinyl sulfones via 1,2-rearrangement or 1,5-CH insertion respectively. In benzyl sulfinates, 1,5-CH insertion is not possible so addition to the aromatic ring occurs followed by ring expansion to generate novel bicyclic sulfones.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Schools: | School of Applied Sciences |
| Related URLs: | |
| Depositing User: | Wesley Moran |
| Date Deposited: | 22 Mar 2016 15:54 |
| Last Modified: | 28 Mar 2018 08:46 |
| URI: | http://eprints.hud.ac.uk/id/eprint/27923 |
Available Versions of this Item
- Preparation of Alkyl Alkynyl Sulfones and Cyclic Vinyl Sulfones from Alkynyl(aryl)iodonium Salts. (deposited 22 Mar 2016 15:54) [Currently Displayed]
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