Allosteric pitch length tuning of a dinuclear double helicate

Baylies, Christian J., Jeffery, John C., Miller, T.A., Moon, Ryan, Rice, Craig R. and Riis-Johannessen, T. (2005) Allosteric pitch length tuning of a dinuclear double helicate. Chemical Communications. pp. 4158-4160. ISSN 1364-548X

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Abstract

Self assembly of the ditopic ligand L1 with Cu2+ gives the dinuclear double helicate [Cu2(L1)2]4+, which can further coordinate s-block cations. This coordination alters the helicate pitch to a variety of different lengths depending on the size and charge of the guest cation.

Item Type:	Article
Additional Information:	UoA 18 (Chemistry) This journal is © The Royal Society of Chemistry 2005
Subjects:	Q Science > QD Chemistry
Schools:	School of Applied Sciences School of Applied Sciences > Materials and Catalysis Research Centre
Related URLs:	Author
References:	1 J.-M. Lehn, Supramolecular Chemistry, VCH, Weinheim, 1995; J. W. Steed and J. L. Atwood, Supramolecular Chemistry, John Wiley and Sons, Chichester, 2000; M. J. Hannon and L. J. Childs, Supramol. Chem., 2004, 16, 7; M. Albrecht, Chem. Rev., 2001, 101, 3547; M. Albrecht, Chem. Soc. Rev., 1998, 27, 281; C. Piguet, G. Bernardinelli and G. Hopfgartner, Chem. Rev., 1997, 97, 2005; E. C. Constable, in Comprehensive Supramolecular Chemistry; Polynuclear Transition Metal Helicates, ed J.-P. Sauvage, Elsevier, Oxford, 1996, vol. 9, pp. 213. 2 E. C. Riesgo,Y.Z.Hu andR.P.Thummel, Inorg. Chem., 2003, 42, 6648. 3 C. R. Rice, S.Wo¨rl, J. C. Jeffery, R. L. Paul and M. D. Ward, Chem. Commun., 2000, 1529; C. R. Rice, S. Wo¨rl, J. C. Jeffery, R. L. Paul and M. D. Ward, J. Chem. Soc., Dalton Trans., 2001, 550. 4 C. J. Baylies, L. P. Harding, J. C. Jeffery, T. Riis-Johannessen and C. R. Rice, Angew. Chem. Int. Ed., 2004, 43, 4515. 5 A. L. Spek, J. Appl. Crystallogr., 2003, 36, 7.
Depositing User:	Briony Heyhoe
Date Deposited:	13 Jul 2007
Last Modified:	28 Aug 2021 23:33
URI:	http://eprints.hud.ac.uk/id/eprint/260

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