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Diborane(4) compounds incorporating thio- and seleno-carboranyl groups

Norman, Nicholas C., Orpen, A. Guy, Quayle, Michael J. and Rice, Craig R. (2000) Diborane(4) compounds incorporating thio- and seleno-carboranyl groups. New Journal of Chemistry, 24 (11). pp. 837-839. ISSN 11440546

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The reaction between B2(NMe2)4 and the carborane dithiol C2B10H10(SH)2, followed by addition of HCl affords the [NH2Me2]+ salt of the dianion [B2Cl2(S2C2B10H10)2]2–, which has been characterised by X-ray crystallography. A similar reaction utilising the carborane diselenol C2B10H10(SeH)2 (generated in situ) afforded a compound containing the dianion [B2(Se2C2B10H10)3]2–.

Item Type: Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
School of Applied Sciences > Materials and Catalysis Research Centre
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Depositing User: Sara Taylor
Date Deposited: 17 Oct 2008 15:25
Last Modified: 28 Aug 2021 10:42


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