Camp, Jason and Craig, Donald. (2009) Reactivity of dearomatised furans synthesized via the decarboxylative Claisen rearrangement. Tetrahedron Letters, 50 (26). pp. 3503-3508. ISSN 0040-4039
Metadata only available from this repository.Abstract
The decarboxylative Claisen rearrangement (dCr) reaction of 1-(furan-2-yl)ethyl 2-tosylacetate afforded 2-ethylidene-3-(tosylmethyl)-2,3-dihydrofuran. Reaction of the dearomatized heterocycle with a variety of electrophiles gave addn. products with excellent syn-diastereoselectivity. The furanol adducts were then utilized as functionalized scaffolds for a series of subsequent transformations. [on SciFinder(R)]
Item Type: | Article |
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Additional Information: | Unmapped bibliographic data: PY - 2009/// [EPrints field already has value set] M3 - 10.1016/j.tetlet.2009.03.091 [Field not mapped to EPrints] JA - Tetrahedron Lett. [Field not mapped to EPrints] |
Uncontrolled Keywords: | decarboxylative Claisen rearrangement furanylethyl tosylacetate, ethylidenetosylmethyldihydrofuran prepn stereoselective reaction electrophile, furan ethylidenetosylmethyldihydro prepn stereoselective reaction electrophile |
Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
Schools: | School of Applied Sciences |
Related URLs: | |
Depositing User: | Sara Taylor |
Date Deposited: | 13 Nov 2014 16:53 |
Last Modified: | 28 Aug 2021 11:43 |
URI: | http://eprints.hud.ac.uk/id/eprint/22278 |
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