Chung, William, Lindovska, Petra and Camp, Jason (2011) A one-pot synthesis of α-formyl-α-allylacetates via nucleophilic catalysis. Tetrahedron Letters, 52 (50). pp. 6785-6787. ISSN 0040-4039
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Official URL: http://dx.doi.org/10.1016/j.tetlet.2011.10.035
Abstract
A step-economical one-pot nucleophilic catalysis/thermal Claisen rearrangement protocol for the direct synthesis of α-formyl-α-allylacetates from allylic alcs. and activated alkynes has been developed. The product α-formyl-α-allylacetates were further reacted in situ to give either protected enol ethers or β-hydroxy-4-pentenoates. [on SciFinder(R)]
Item Type: | Article |
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Additional Information: | Unmapped bibliographic data: PY - 2011/// [EPrints field already has value set] M3 - 10.1016/j.tetlet.2011.10.035 [Field not mapped to EPrints] JA - Tetrahedron Lett. [Field not mapped to EPrints] |
Uncontrolled Keywords: | allylic alc activated alkyne nucleophilic catalysis addn Claisen rearrangement, formyl allylacetate prepn protection redn |
Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
Schools: | School of Applied Sciences |
Related URLs: | |
Depositing User: | Sara Taylor |
Date Deposited: | 13 Nov 2014 16:33 |
Last Modified: | 28 Aug 2021 11:43 |
URI: | http://eprints.hud.ac.uk/id/eprint/22274 |
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