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A one-pot synthesis of α-formyl-α-allylacetates via nucleophilic catalysis.

Chung, William, Lindovska, Petra and Camp, Jason (2011) A one-pot synthesis of α-formyl-α-allylacetates via nucleophilic catalysis. Tetrahedron Letters, 52 (50). pp. 6785-6787. ISSN 0040-4039

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A step-economical one-pot nucleophilic catalysis/thermal Claisen rearrangement protocol for the direct synthesis of α-formyl-α-allylacetates from allylic alcs. and activated alkynes has been developed. The product α-formyl-α-allylacetates were further reacted in situ to give either protected enol ethers or β-hydroxy-4-pentenoates. [on SciFinder(R)]

Item Type: Article
Additional Information: Unmapped bibliographic data: PY - 2011/// [EPrints field already has value set] M3 - 10.1016/j.tetlet.2011.10.035 [Field not mapped to EPrints] JA - Tetrahedron Lett. [Field not mapped to EPrints]
Uncontrolled Keywords: allylic alc activated alkyne nucleophilic catalysis addn Claisen rearrangement, formyl allylacetate prepn protection redn
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
Related URLs:
Depositing User: Sara Taylor
Date Deposited: 13 Nov 2014 16:33
Last Modified: 28 Aug 2021 11:43


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