Multifaceted catalysis approach to nitrile activation: direct synthesis of halogenated allyl amides from allylic alcohols.

Lester, Roy P., Dunsford, Jay J. and Camp, Jason (2013) Multifaceted catalysis approach to nitrile activation: direct synthesis of halogenated allyl amides from allylic alcohols. Organic & Biomolecular Chemistry, 11 (43). pp. 7472-7476. ISSN 1477-0520

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Abstract

Allyl amides were synthesized from the reaction of allyl alcs. and halogenated nitriles using a platinum multifaceted catalysis approach in which both the nucleophilic addn. and subsequent [3,3]-sigmatropic rearrangement steps of the process were catalyzed by the same complex. Addnl., 1H/13C{1H} NMR and GC studies provided the first insights into the mechanism of this transformation. [on SciFinder(R)]

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URI:

https://eprints.hud.ac.uk/id/eprint/22269

Title:

Multifaceted catalysis approach to nitrile activation: direct synthesis of halogenated allyl amides from allylic alcohols.

Creators:

Lester, Roy P., Dunsford, Jay J. and Camp, Jason

Identification Number:

https://doi.org/10.1039/c3ob41692e

Official URL:

http://dx.doi.org/10.1039/C3OB41692E

Date:

2013

Subjects:

Q Science > Q Science (General)
Q Science > QD Chemistry

Schools:

School of Applied Sciences

Additional Information:

Unmapped bibliographic data: PY - 2013/// [EPrints field already has value set] M3 - 10.1039/c3ob41692e [Field not mapped to EPrints] JA - Org. Biomol. Chem. [Field not mapped to EPrints]

Uncontrolled Keywords:

halogenated nitrile allyl alc nucleophilic addn sigmatropic rearrangement mechanism, allyl amide halogenated prepn multifaceted platinum catalyst

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Item Type:

Article

Depositing User:

Sara Taylor

Date Deposited:

13 Nov 2014 09:57

Revision:

Last Modified:

28 Aug 2021 11:43