Lester, Roy P., Dunsford, Jay J. and Camp, Jason (2013) Multifaceted catalysis approach to nitrile activation: direct synthesis of halogenated allyl amides from allylic alcohols. Organic & Biomolecular Chemistry, 11 (43). pp. 7472-7476. ISSN 1477-0520

Allyl amides were synthesized from the reaction of allyl alcs. and halogenated nitriles using a platinum multifaceted catalysis approach in which both the nucleophilic addn. and subsequent [3,3]-sigmatropic rearrangement steps of the process were catalyzed by the same complex. Addnl., 1H/13C{1H} NMR and GC studies provided the first insights into the mechanism of this transformation. [on SciFinder(R)]

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