Patmore, Nathan J., Mahon, Mary F. and Weller, Andrew S. (2003) Bi- and tri-metallic {Cp*RhCl} fragments partnered with carborane monoanions [CB11H6Y6]? (Y = H, Br): control of nuclearity by choice of anion. Applied Organometallic Chemistry, 17 (6-7). pp. 388-392. ISSN 0268-2605
Metadata only available from this repository.Abstract
Reaction of [Cp*RhCl2]2 (Cp* = pentamethylcyclopentadienyl) with Ag[closo-CB11H12] affords the dinuclear salt [Cp*RhCl]2[CB11H12]2 (1), which in the solid state reveals a single carborane anion interacting with two {Cp*RhCl} fragments, via two B[BOND]H[BOND]Rh interactions. With Ag[closo-CB11H6Br6] the trimetallic complex [{Cp*Rh(µ2-Cl)} 3(µ3-Cl)][closo-CB11H6Br6]2 (2) results. In the solid state, three metal fragments and four chloride ligands form seven-corners of a cube, and the eighth vertex is completed by a cage C[BOND]H unit hydrogen bonded to three bridging chloride ligands.
Item Type: | Article |
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Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
Schools: | School of Applied Sciences |
Related URLs: | |
Depositing User: | Sharon Beastall |
Date Deposited: | 03 Apr 2014 10:37 |
Last Modified: | 28 Aug 2021 11:36 |
URI: | http://eprints.hud.ac.uk/id/eprint/19984 |
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