Barybin, Mikhail V., Chisholm, Malcolm H., Patmore, Nathan J., Robinson, Randall E. and Singh, Namrata (2007) Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-Carboethoxy-2-carboxylatoazulene ligands. Chemical Communications (35). pp. 3652-3654. ISSN 1359-7345
Abstract

The preparation and molecular structure of a W24+-quadruply bonded complex is reported wherein two mutually trans azulene-2-carboxylato ligands are shown to be strongly coupled by ligand π–M2δ–ligand π conjugation.

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