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Preparation and ring-opening reactions ofN-diphenylphosphinyl vinyl aziridines

Jarvis, Ashley N., McLaren, Andrew B., Osborn, Helen M. I. and Sweeney, Joseph B. (2013) Preparation and ring-opening reactions ofN-diphenylphosphinyl vinyl aziridines. Beilstein Journal of Organic Chemistry, 9. pp. 852-859. ISSN 1860-5397

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Predominantly (E)-N-diphenylphosphinyl vinyl aziridines are prepared by a reaction of N-diphenylphosphinyl imines with α-bromoallyllithium in the presence of freshly fused ZnCl2. These aziridines undergo a ring-opening reaction with a variety of carbon and heteronucleophiles, in good yield, and generally with good regioselectivity.

Item Type: Article
Uncontrolled Keywords: aziridines; catalytic; heterocycles; palladium; ring opening
Subjects: Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Graham Stone
Date Deposited: 18 Sep 2013 16:13
Last Modified: 28 Aug 2021 19:42


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