Jarvis, Ashley N., McLaren, Andrew B., Osborn, Helen M. I. and Sweeney, Joseph B. (2013) Preparation and ring-opening reactions ofN-diphenylphosphinyl vinyl aziridines. Beilstein Journal of Organic Chemistry, 9. pp. 852-859. ISSN 1860-5397
![]() |
PDF
Available under License Creative Commons Attribution. Download (317kB) |
Abstract
Predominantly (E)-N-diphenylphosphinyl vinyl aziridines are prepared by a reaction of N-diphenylphosphinyl imines with α-bromoallyllithium in the presence of freshly fused ZnCl2. These aziridines undergo a ring-opening reaction with a variety of carbon and heteronucleophiles, in good yield, and generally with good regioselectivity.
Item Type: | Article |
---|---|
Uncontrolled Keywords: | aziridines; catalytic; heterocycles; palladium; ring opening |
Subjects: | Q Science > QD Chemistry |
Schools: | School of Applied Sciences |
Related URLs: | |
Depositing User: | Graham Stone |
Date Deposited: | 18 Sep 2013 16:13 |
Last Modified: | 28 Aug 2021 19:42 |
URI: | http://eprints.hud.ac.uk/id/eprint/18407 |
Downloads
Downloads per month over past year
Repository Staff Only: item control page
![]() |
View Item |