Preparation and ring-opening reactions ofN-diphenylphosphinyl vinyl aziridines

Jarvis, Ashley N., McLaren, Andrew B., Osborn, Helen M. I. and Sweeney, Joseph B. (2013) Preparation and ring-opening reactions ofN-diphenylphosphinyl vinyl aziridines. Beilstein Journal of Organic Chemistry, 9. pp. 852-859. ISSN 1860-5397

PDF Available under License Creative Commons Attribution. Download (317kB)

Abstract

Predominantly (E)-N-diphenylphosphinyl vinyl aziridines are prepared by a reaction of N-diphenylphosphinyl imines with α-bromoallyllithium in the presence of freshly fused ZnCl2. These aziridines undergo a ring-opening reaction with a variety of carbon and heteronucleophiles, in good yield, and generally with good regioselectivity.

Item Type:	Article
Uncontrolled Keywords:	aziridines; catalytic; heterocycles; palladium; ring opening
Subjects:	Q Science > QD Chemistry
Schools:	School of Applied Sciences
Related URLs:	Author
Depositing User:	Graham Stone
Date Deposited:	18 Sep 2013 16:13
Last Modified:	01 Dec 2016 09:18
URI:	http://eprints.hud.ac.uk/id/eprint/18407

Downloads

Repository Staff Only: item control page

View Item