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Oxidative Rearrangement of Tertiary Propargylic Alcohols

Rodríguez, Arantxa and Moran, Wesley J. (2013) Oxidative Rearrangement of Tertiary Propargylic Alcohols. Synlett, 24 (1). pp. 102-104. ISSN 0936-5214

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An oxidative rearrangement of tertiary alcohols mediated by m-CPBA is described that generates tetrasubstituted alkenes with a carboxylic acid substituent. The mechanism of the reaction is proposed to proceed through epoxidation of the alkyne to form an oxirene that undergoes a 1,2-aryl shift.

Item Type: Article
Subjects: Q Science > QD Chemistry
Schools: School of Applied Sciences
Related URLs:
Depositing User: Wesley Moran
Date Deposited: 06 Dec 2012 15:38
Last Modified: 28 Aug 2021 11:24


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