Sweeney, Joseph B., Haughan, Alan F., Knight, J.R. and Thobhani, Smita (2007) Hydroxyselanylation of acyloxycyclohex-3-enes. Tetrahedron, 63 (12). pp. 2729-2737. ISSN 0040-4020
Metadata only available from this repository.Abstract
In contrast to the corresponding hydroxyiodination reactions, the reaction of acetoxycyclohex-2-ene 1 with N-PSP in the presence of water shows little regiocontrol, but is highly diastereoselective. However, the same reaction of the (R)-phenylglycinate derivative of (±)-cyclohexen-3-ol is highly diastereoselective, and regioselective. A hydrogen-bonding interaction is proposed to rationalize these differing selectivities.
Item Type: | Article |
---|---|
Subjects: | Q Science > QD Chemistry |
Schools: | School of Applied Sciences |
Related URLs: | |
Depositing User: | Joseph Sweeney |
Date Deposited: | 09 Oct 2012 08:55 |
Last Modified: | 28 Aug 2021 11:22 |
URI: | http://eprints.hud.ac.uk/id/eprint/15426 |
Downloads
Downloads per month over past year
Repository Staff Only: item control page
![]() |
View Item |