Heath, Peter, Roberts, Edward, Sweeney, Joseph B., Wessel, Hans Peter and Workman, James A. (2003) Copper(II)-Catalyzed [2,3]-Sigmatropic Rearrangement ofN-Methyltetrahydropyridinium Ylids. The Journal of Organic Chemistry, 68 (10). pp. 4083-4086. ISSN 0022-3263
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Official URL: http://dx.doi.org/10.1021/jo034147v
DOI: 10.1021/jo034147v
Abstract
A ring-contractive and highly diastereoselective [2,3]-sigmatropic rearrangement occurs when N-methyl-1,2,3,6-tetrahydropyridine is treated with sub-stoichiometric amounts of copper or rhodium salts, in the presence of ethyl diazoacetate, giving ethyl cis-N-methyl-3-ethenyl proline (4).
Item Type: | Article |
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Subjects: | Q Science > QD Chemistry |
Schools: | School of Applied Sciences > Biomolecular Sciences Research Centre |
Related URLs: | |
Depositing User: | Joseph Sweeney |
Date Deposited: | 18 Oct 2012 10:46 |
Last Modified: | 28 Aug 2021 11:22 |
URI: | http://eprints.hud.ac.uk/id/eprint/15277 |
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