Computing and Library Services - delivering an inspiring information environment

Substituent effects in hydroxyiodination of 1,2-diacyloxycyclohex-3-enes

Sweeney, Joseph B., Knight, J.R. and Thobhani, Smita (2006) Substituent effects in hydroxyiodination of 1,2-diacyloxycyclohex-3-enes. Tetrahedron, 62 (50). pp. 11565-11571. ISSN 0040-4020

Metadata only available from this repository.


The reaction of 1,2-diacyloxycyclohex-3-enes with iodinating agents in the presence of water has been investigated. The process is inherently diastereoselective, with many reactions giving only two of the four possible diastereoisomers which could be obtained. However, the regiocontrol is variable: highest selectivities are observed when pivalates are present on the periphery of the cycloalkene, when single regio- and diastereoisomers are obtained from the reactions.

Item Type: Article
Subjects: Q Science > QD Chemistry
Schools: School of Applied Sciences
Related URLs:
Depositing User: Joseph Sweeney
Date Deposited: 18 Oct 2012 11:23
Last Modified: 28 Aug 2021 11:22


Downloads per month over past year

Repository Staff Only: item control page

View Item View Item

University of Huddersfield, Queensgate, Huddersfield, HD1 3DH Copyright and Disclaimer All rights reserved ©