Gabbutt, Christopher D., Heron, B. Mark, Hursthouse, Michael B. and Abdul Malik, K. M. (2000) Conjugate addition of a phosphorus ylide to 3-cyanochromone. Phosphorus, Sulfur, and Silicon and the Related Elements, 166 (1). pp. 99-109. ISSN 1042-6507
Metadata only available from this repository.Abstract
Reaction of 3-cyanochromone with methylenetriphenylphosphorane yields the stabilized ylide (4) by way of a conjugate addition and subsequent ring opening. Variable temperature 1H NMR spectroscopy indicates that this ylide undergoes rapid conformational interconversion at ambient temperature. X-ray crystallography established that (4) exists as the (E) isomer in the solid state.
Item Type: | Article |
---|---|
Subjects: | Q Science > Q Science (General) Q Science > QD Chemistry |
Schools: | School of Applied Sciences |
Related URLs: | |
Depositing User: | Sharon Beastall |
Date Deposited: | 25 Sep 2012 09:19 |
Last Modified: | 05 Apr 2018 12:15 |
URI: | http://eprints.hud.ac.uk/id/eprint/15041 |
Downloads
Downloads per month over past year
Repository Staff Only: item control page
![]() |
View Item |