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The directed lithiation of some 3-acylchromone acetals

Daia, G.Elena, Gabbutt, Christopher D., Hepworth, John D., Heron, B. Mark, Hibbs, David E. and Hursthouse, Michael B. (1998) The directed lithiation of some 3-acylchromone acetals. Tetrahedron Letters, 39 (10). pp. 1215-1218. ISSN 0040-4039

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3-Acylchromone acetals are lithiated at C-2. Subsequent electrophilic trapping gives chromones 4 together with a ring-contracted dimer 6. During the formation of some acetals, an acid-catalysed rearrangement to a 2-substituted 3-formylchromone acetal is observed.

Item Type: Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Sharon Beastall
Date Deposited: 20 Sep 2012 12:28
Last Modified: 28 Aug 2021 11:21


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