Synthesis and X-ray structures of cadmium-containing dinuclear double helicates derived from ligands containing N-oxide units

Bokolinis, Georgios, Riis-Johannessen, T., Jeffery, John C. and Rice, Craig R. (2008) Synthesis and X-ray structures of cadmium-containing dinuclear double helicates derived from ligands containing N-oxide units. New Journal of Chemistry, 32 (1). pp. 115-119. ISSN 11440546

Abstract

The syntheses of two novel polydentate pyridyl-thiazolyl ligands which contain an N-oxide unit on the central pyridyl ring are reported. Reaction of either of these ligands with Cd(ClO4)2·6H2O results in the formation of a dinuclear double helicate. The solid state structures of these transition metal helicates demonstrate the ability of the N-oxide unit to partition the ligands into two separate binding domains

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