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Synthesis of densely functionalised arenes using [2 + 2 + 2] cycloaddition reactions

Clayden, Jonathan and Moran, Wesley J. (2007) Synthesis of densely functionalised arenes using [2 + 2 + 2] cycloaddition reactions. Organic & Biomolecular Chemistry, 5 (7). p. 1028. ISSN 14770520

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Abstract

Rh(I)–catalysed [2 + 2 + 2] cycloaddition allows the synthesis of aryl ethers and diaryl methanes containing a high degree of steric hindrance from relatively simple diyne and alkyne precursors. The diarylmethanes made in this way show no evidence in their NMR spectra, however, of rotational restriction.

Item Type: Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Sara Taylor
Date Deposited: 30 Jun 2008 15:09
Last Modified: 02 Jun 2009 13:39
URI: http://eprints.hud.ac.uk/id/eprint/947

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