Intra-and inter-molecular general base catalysis in the aminolysis of benzylpenicillin

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Martin, Anthony F., Morris, Jeffrey J. and Page, Michael I. (1976) Intra-and inter-molecular general base catalysis in the aminolysis of benzylpenicillin. Chemical Communications (13). pp. 495-496. ISSN 1359-7345

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Official URL: http://dx.doi.org/10.1039/C39760000495

DOI: 10.1039/C39760000495

Abstract

The rate law for the aminolysis of benzylpenicillin is obtained and Brønsted -values indicate that the general-base-catalysed reaction occurs with a stepwise proton-transfer step; intramolecular general base catalysis occurs in the reaction of ethylenediamine with penicillin.

Item Type:	Article
Subjects:	Q Science > Q Science (General) Q Science > QD Chemistry
Schools:	School of Applied Sciences
Related URLs:	Author
Depositing User:	Sharon Beastall
Date Deposited:	11 Nov 2009 13:15
Last Modified:	11 Nov 2009 13:15
URI:	http://eprints.hud.ac.uk/id/eprint/6177

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