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Intra-and inter-molecular general base catalysis in the aminolysis of benzylpenicillin

Martin, Anthony F., Morris, Jeffrey J. and Page, Michael I. (1976) Intra-and inter-molecular general base catalysis in the aminolysis of benzylpenicillin. Chemical Communications (13). pp. 495-496. ISSN 1359-7345

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Abstract

The rate law for the aminolysis of benzylpenicillin is obtained and Brønsted -values indicate that the general-base-catalysed reaction occurs with a stepwise proton-transfer step; intramolecular general base catalysis occurs in the reaction of ethylenediamine with penicillin.

Item Type: Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Sharon Beastall
Date Deposited: 11 Nov 2009 13:15
Last Modified: 11 Nov 2009 13:15
URI: http://eprints.hud.ac.uk/id/eprint/6177

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