Equilibria between enamine and B-unsaturated imine in cephalosporin hydrolysis

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Buckwell, Stephen C., Page, Michael I. and Longridge, Jethro L. (1986) Equilibria between enamine and B-unsaturated imine in cephalosporin hydrolysis. Chemical Communications (13). pp. 1039-1040. ISSN 1359-7345

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Official URL: http://dx.doi.org/10.1039/C39860001039

DOI: 10.1039/C39860001039

Abstract

The normal product of hydrolysis of cephalosporins with a leaving group at C-3 is an ,-unsaturated imine which is demonstrated to be in equilibrium with its precursor, an enamine; the equilibrium constants for this process are reported for thiolate anions which generate a Bronsted lg of 0.71

Item Type:	Article
Subjects:	Q Science > Q Science (General) Q Science > QD Chemistry
Schools:	School of Applied Sciences
Related URLs:	Author
Depositing User:	Sharon Beastall
Date Deposited:	11 Nov 2009 12:25
Last Modified:	11 Nov 2009 12:25
URI:	http://eprints.hud.ac.uk/id/eprint/6171

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