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Equilibria between enamine and B-unsaturated imine in cephalosporin hydrolysis

Buckwell, Stephen C., Page, Michael I. and Longridge, Jethro L. (1986) Equilibria between enamine and B-unsaturated imine in cephalosporin hydrolysis. Chemical Communications (13). pp. 1039-1040. ISSN 1359-7345

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Abstract

The normal product of hydrolysis of cephalosporins with a leaving group at C-3 is an ,-unsaturated imine which is demonstrated to be in equilibrium with its precursor, an enamine; the equilibrium constants for this process are reported for thiolate anions which generate a Bronsted lg of 0.71

Item Type: Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Sharon Beastall
Date Deposited: 11 Nov 2009 12:25
Last Modified: 11 Nov 2009 12:25
URI: http://eprints.hud.ac.uk/id/eprint/6171

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