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Reaction rates and thermodynamic equilibration of tetrahedral intermediates: the alcoholysis of cephalosporins

Davies, Karen J. and Page, Michael I. (1990) Reaction rates and thermodynamic equilibration of tetrahedral intermediates: the alcoholysis of cephalosporins. Chemical Communications (20). pp. 1448-1450. ISSN 1359-7345

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Abstract

The rate of reaction of cephalosporins with alkoxide ions shows general acid-catalysed inhibition, which is attributed to the trapping of the anionic tetrahedral intermediate (T–) by proton donors to give the thermodynamically more stable neutral intermediate To at a rate which is faster than breakdown of T–.

Item Type: Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Sharon Beastall
Date Deposited: 06 Nov 2009 10:06
Last Modified: 06 Nov 2009 10:06
URI: http://eprints.hud.ac.uk/id/eprint/6118

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