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Large rate enhancement for the hydrolysis of a four-membered ring phosphonamidate

Laws, Andrew P., Stone, J.R. and Page, Michael I. (1994) Large rate enhancement for the hydrolysis of a four-membered ring phosphonamidate. Chemical Communications (10). pp. 1223-1224. ISSN 1359-7345

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Abstract

Unlike -lactams a four-membered cyclic 1,2-azaphosphetidine shows enhanced hydrolytic reactivity compared with an acyclic analogue; the cyclic phosphonamidate 3 undergoes hydroxide-ion catalysed hydrolysis in water with endocyclic P–N fission; a corresponding acyclic derivative hydrolyses with P–O fission in basic solution, the rate difference between the cyclic and acyclic structures for P–N fission is greater than 5 × 108

Item Type: Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
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Depositing User: Sharon Beastall
Date Deposited: 05 Nov 2009 14:04
Last Modified: 05 Nov 2009 14:04
URI: http://eprints.hud.ac.uk/id/eprint/6101

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