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High-nuclearity homoleptic and heteroleptic coordination cages based on tetra-capped truncated tetrahedral and cuboctahedral metal frameworks

Argent, Stephen P., Adams, Harry, Riis-Johannessen, Thomas, Jeffery, John C., Harding, Lindsay P. and Ward, Michael D. (2005) High-nuclearity homoleptic and heteroleptic coordination cages based on tetra-capped truncated tetrahedral and cuboctahedral metal frameworks. Journal of the American Chemical Society, 128 (1). pp. 72-73. ISSN 1520-5126

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Abstract

Two new types of coordination cage have been prepared and structurally characterized: [M16(-L1)24]X32 are based on a tetra-capped truncated tetrahedral core and have a bridging ligand L1 along each of the 24 edges; [M12(-L1)12(3-L2)4]X24 are based on a cuboctahedral core which is supported by a combination of face-capping ligands L2 and edge-bridging ligands L1. The difference between the two illustrates how combinations of ligands with different coordination modes can generate coordination cages which are not available using one ligand type on its own

Item Type: Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
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(1) (a) Swiegers, G. F.; Malefetse, T. J. Coord. Chem. ReV. 2002, 225, 91.
(b) Fujita, M.; Tominaga, M.; Hori, A.; Therrien, B. Acc. Chem. Res.
2005, 38, 369. (c) Fiedler, D.; Leung, D. H.; Bergman, R. G.; Raymond,
K. N. Acc. Chem. Res. 2005, 38, 349. (d) Schweiger, M.; Yamamoto, T.;
Stang, P. J.; Blaser, D.; Boese, R. J. Org. Chem. 2005, 70, 4861.
(2) (a) Caulder, D. L.; Powers, R. E.; Parac, T. N.; Raymond, K. N. Angew.
Chem., Int. Ed. 1998, 37, 1840. (b) Argent, S. P.; Riis-Johannessen, T.;
Jeffery, J. C.; Harding, L. P.; Ward, M. D. Chem. Commun. 2005, 4647
and references therein. (c) Saalfrank, R. W.; Demleitner, B.; Glaser, H.;
Maid, H.; Bathelt, D.; Hampel, F.; Bauer, W.; Teichert, M. Chem. Eur.
J. 2002, 8, 2679. (d) Clegg, J. K.; Lindoy, L. F.; Moubaraki, B.; Murray,
K. S.; McMurtrie, J. C. Dalton Trans. 2004, 2417.
(3) Bell, Z. R.; Harding, L. P.; Ward, M. D. Chem. Commun. 2003, 2432.
(4) Bell, Z. R.; Jeffery, J. C.; McCleverty, J. A.; Ward, M. D. Angew. Chem.,
Int. Ed. 2002, 41, 2515.
(5) (a) Amoroso, A. J.; Jeffery, J. C.; Jones, P. L.; McCleverty, J. A.; Thornton,
P.; Ward, M. D. Angew. Chem., Int. Ed. Engl. 1995, 34, 1443. (b)
Saalfrank, R. W.; Glaser, H.; Demleitner, B.; Hampel, F.; Chowdhry, M.
M.; Schunemann, V.; Trautwein, A. X.; Vaughan, G. B. M.; Yeh, R.;
Davis, A. V.; Raymond, K. N. Chem. Eur. J. 2002, 8, 493.
(6) Hiraoka, S.; Kubota, Y.; Fujita, M. Chem. Commun. 2000, 1509.
(7) Olenyuk, B.; Whiteford, J. A.; Fechtenko¨tter, A.; Stang, P. J. Nature 1999,
398, 796.
(8) (a) Tominaga, M.; Suzuki, K.; Kawano, M.; Kusukawa, T.; Ozeki, T.;
Sakamoto, S.; Yamaguchi, K.; Fujita, M. Angew. Chem., Int. Ed. Engl.
2004, 43, 5621. (b) Tominaga, M.; Suzuki, K.; Murase, T.; Fujita, M. J.
Am. Chem. Soc. 2005, 127, 11950. (c) Eddaoudi, M.; Kim, J.; Wachter,
J. B.; Chae, H. K.; O’Keeffe, M.; Yaghi, O. M. J. Am. Chem. Soc. 2001,
123, 4368. (d) Abrahams, B. F.; Egan, S. J.; Robson, R. J. Am. Chem.
Soc. 1999, 121, 3535.
JA056993O

Depositing User: Sara Taylor
Date Deposited: 13 Mar 2008 11:33
Last Modified: 30 Oct 2008 16:21
URI: http://eprints.hud.ac.uk/id/eprint/566

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