Search:
Computing and Library Services - delivering an inspiring information environment

A closed molecular cube and an open book: two different products from assembly of the same metal salt and bridging ligand

Argent, Stephen P., Adams, Harry, Harding, Lindsay P. and Ward, Michael D. (2006) A closed molecular cube and an open book: two different products from assembly of the same metal salt and bridging ligand. Dalton Transactions, 2006 (4). pp. 542-544. ISSN 1477-9226

Metadata only available from this repository.

Abstract

Reaction of the bis-bidentate bridging ligand L1 with Co(ClO4)2 or Zn(BF4)2 affords a mixture of complexes [M8(L1)12]X16 and [M6(L1)9]X12 having the same metal : ligand ratio: the former is a molecular cube with a metal ion at each vertex and a bridging ligand spanning each edge, whereas the latter has a metal framework like that of an open book containing cross-linked double helical metal–ligand subunits.

Item Type: Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Schools: School of Applied Sciences
Related URLs:
References:

1 Reviews: (a) G. F. Swiegers and T. J. Malefetse, Coord. Chem. Rev.,
2002, 225, 91; (b) M. Fujita, M. Tominaga, A. Hori and B. Therrien,
Acc. Chem. Res., 2005, 38, 369; (c) D. Fiedler, D. H. Leung, R. G.
Bergman and K. N. Raymond, Acc. Chem. Res., 2005, 38, 349; (d) M.
Yoshizawa and M. Fujita, Pure Appl. Chem., 2005, 77, 1107.
2 Representative recent examples:(a) M. Schweiger, T. Yamamoto, P. J.
Stang, D. Blaser and R. Boese, J. Org. Chem., 2005, 70, 4861; (b) R. W.
Saalfrank, B. Demleitner, H. Glaser, H. Maid, D. Bathelt, F. Hampel,
W. Bauer and M. Teichert, Chem. Eur. J., 2002, 8, 2679; (c) J. K.
Clegg, L. F. Lindoy, B. Moubaraki, K. S. Murray and J. McMurtrie,
Dalton Trans., 2004, 2417; (d) A. V. Davis and K. N. Raymond, J. Am.
Chem. Soc., 2005, 127, 7912; (e) K. Nakabayashi, M. Kawano and M.
Fujita, Angew. Chem., Int. Ed., 2005, 44, 5322; (f) S. Karthikeyan and
V. Ramamurthy, Tetrahedron Lett., 2005, 46, 4495; (g) D. J. Bray, L. L.
Liao, B. Antonioli, K. Gloe, L. F. Lindoy, J. C. McMurtrie, G.Wei and
X.Y. Zhang, Dalton Trans., 2005, 2082; (h) I.M.Muller andD. Moller,
Angew. Chem., Int. Ed., 2005, 44, 2969; (i) T. Haino,M. Kobayashi, M.
Chikaraishi and Y. Fukazawa, Chem. Commun., 2005, 2321.
3 B. Hasenknopf, J.-M. Lehn, B. O. Kneisel, G. Baum and D. Fenske,
Angew. Chem., Int. Ed. Engl., 1996, 35, 1838; B. Hasenknopf, J.-M.
Lehn, N. Boumidiene, A. Dupont-Gervais, A. Van Dorsselaer, B.
Kneisel and D. Fenske, J. Am. Chem. Soc., 1997, 119, 10956.
4 M. Scherer, D. L. Caulder, D.W. Johnson and K. N. Raymond, Angew.
Chem., Int. Ed., 1999, 38, 1588; M. Albrecht, I. Janser, J. Runsink, G.
Raabe, P.Weis and R. Frohlich, Angew. Chem., Int. Ed., 2004, 43, 6662.
5 S. J. Park,D. M. Shin, S. Sakamoto, K. Yamaguchi, Y.K. Chung,M. S.
Lah and J. I. Hong, Chem. Eur. J., 2004, 11, 235.
6 G. Baum, E. C. Constable, D. Fenske, C. E. Housecroft and T. Kulke,
Chem. Commun., 1999, 195; F. Tuna, J. Hamblin, A. Jackson, G.
Clarkson, N.W. Alcock andM. J. Hannon, Dalton Trans., 2003, 2141;
C. S. Campos-Fernandez, B. L. Schottel, H. T. Chifotides, J. K. Bera, J.
Basca, J. M. Koomen, D. H. Russell and K. R. Dunbar, J. Am. Chem.
Soc., 2005, 127, 12909.
7 J. R. Nitschke and J.-M. Lehn, Proc. Natl. Acad. Sci. USA, 2003, 100,
11970.
8 J. S. Fleming, K.L. V. Mann, C.-A. Carraz, E. Psillakis, J. C. Jeffery,
J. A. McCleverty and M. D. Ward, Angew. Chem., Int. Ed., 1998, 37,
1279; R. L. Paul, Z. R. Bell, J. C. Jeffery, J. A. McCleverty and M. D.
Ward, Proc. Natl. Acad. Sci. USA, 2002, 99, 4883; R. L. Paul, Z. R.
Bell, J. C. Jeffery, L. P. Harding, J. A. McCleverty and M. D. Ward,
Polyhedron, 2003, 22, 781; R. L. Paul, S. P. Argent, J. C. Jeffery, L. P.
Harding, J. M. Lynam and M. D. Ward, Dalton Trans., 2004, 3453;
S. P. Argent, T. Riis-Johannessen, J. C. Jeffery, L. P. Harding andM. D.
Ward, Chem. Commun., 2005, 4647.
9 S. P.Argent,H.Adams, T.Riis-Johannessen, J. C. Jeffery, L. P. Harding
andM. D. Ward, J. Am. Chem. Soc., DOI: 10.1021/ja056993o.
10 Z. R. Bell, J. C. Jeffery, J. A. McCleverty and M. D. Ward, Angew.
Chem., Int. Ed., 2002, 41, 2515.
11 Z. R. Bell, L. P. Harding and M.D.Ward, Chem. Commun., 2003, 2432.
12 Z. R. Bell, J. A. McCleverty andM. D.Ward, Aust. J. Chem., 2003, 56,
665.
13 S. Roche, C. Haslam, H. Adams, S. L. Heath and J. A. Thomas, Chem.
Commun., 1998, 1681; K. K. Klausmeyer, T. B. Rauchfuss and S. R.
Wilson, Angew. Chem., Int. Ed., 1998, 37, 1694; B. F. Abrahams, S. J.
Egan and R. Robson, J. Am. Chem. Soc., 1999, 121, 3535; M. C. Hong,
Y. J. Zhao, W. P. Su, R. Cao, M. Fujita, Z. Y. Zhou and A. S. C.
Chan, J. Am. Chem. Soc., 2000, 122, 4819; E. J. Schelter, A. V. Prosvirin
and K. R. Dunbar, J. Am. Chem. Soc., 2004, 126, 15004; Y. Liu, V.
Kravtsov, R. D. Walsh, P. Poddar, H. Srikanth and M. Eddaoudi,
Chem. Commun., 2004, 2806 and refs. therein.

Depositing User: Sara Taylor
Date Deposited: 13 Mar 2008 11:10
Last Modified: 30 Oct 2008 16:23
URI: http://eprints.hud.ac.uk/id/eprint/565

Item control for Repository Staff only:

View Item

University of Huddersfield, Queensgate, Huddersfield, HD1 3DH Copyright and Disclaimer All rights reserved ©