Hanusek, Jifi, Russell, Mark A., Laws, Andrew P. and Page, Michael I. (2007) Evidence for the formation of isothiocyanate during sulphurisation of triphenyl phosphines using xanthane hydride. Tetrahedron Letters, 48 (3). pp. 417-419. ISSN 0040-4039
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Contrary to a previous report, the sulfurisation of triphenylphosphines and trialkyl phosphites by 3-amino-1,2,4-dithiazole-5-thione (xanthane hydride) does not yield carbon disulfide and cyanamide as the additional reaction products but unstable thiocarbamoyl isothiocyanate which has been trapped with nucleophiles.
|Additional Information:||UoA 18 (Chemistry)|
|Subjects:||Q Science > Q Science (General)|
Q Science > QD Chemistry
|Schools:||School of Applied Sciences|
School of Applied Sciences > Biomolecular Sciences Research Centre
1. (a) Eckstein, F.; Gish, G. Trends Biochem. Sci. 1989, 14,
|Depositing User:||Sara Taylor|
|Date Deposited:||04 Feb 2008 10:37|
|Last Modified:||20 Oct 2008 09:50|
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- Evidence for formation of isothiocyanate during sulphurisaton of triphenyl phosphines using xanthane hydride. (deposited 01 Feb 2008 16:40)
- Evidence for the formation of isothiocyanate during sulphurisation of triphenyl phosphines using xanthane hydride. (deposited 04 Feb 2008 10:37)[Currently Displayed]
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