Zawia, Eman and Moran, Wesley J. (2016) Aqueous DMSO Mediated Conversion of (2-(Arylsulfonyl)vinyl)iodonium Salts to Aldehydes and Vinyl Chlorides. Molecules, 21 (8). ISSN 1420-3049
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Vinyl(aryl)iodonium salts are useful compounds in organic synthesis but they are under-utilized and their chemistry is under-developed. Herein is described the solvolysis of some vinyl(phenyl)iodonium salts, bearing an arylsulfonyl group, in aqueous DMSO leading to aldehyde formation. This unusual process is selective and operates under ambient conditions. Furthermore,the addition of aqueous HCl and DMSO to these vinyl(aryl)iodonium salts allows their facile conversion to vinyl chlorides.
|Uncontrolled Keywords:||iodane; hypervalent iodine; solvolysis|
|Subjects:||Q Science > QD Chemistry|
|Schools:||School of Applied Sciences|
|Depositing User:||Wesley Moran|
|Date Deposited:||16 Aug 2016 10:30|
|Last Modified:||10 Dec 2016 17:31|
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