Baty, John and Sinnott, Michael L. (2004) Efficient electrophilic catalysis of 1,5-anhydrocellobiitol hydrolysis by Al(III); implications for the conservation of “rosin-alum” sized paper. Chemical Communications. pp. 866-867. ISSN 1364-548X
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Abstract
Added Al2SO4 greatly accelerates the hydrolysis at 150.0 °C of 1,5-anhydrocellobiitol, a model for the (14) linkages in cellulose, in succinate buffers of room temperature pH 3.05 and 3.35; Ea values for 20 mM AlIII- and H+-catalysed hydrolyses are 109 ± 3 and 140 ± 1 kJ mol–1, respectively.
| Item Type: | Article |
|---|---|
| Additional Information: | UoA 18 (Chemistry) This journal is © The Royal Society of Chemistry 2004 |
| Subjects: | Q Science > QD Chemistry |
| Schools: | School of Applied Sciences School of Applied Sciences > Biomolecular Sciences Research Centre |
| Related URLs: | |
| References: | 1 (a) L. Neimo, in Papermaking Chemistry, ed. L. Neimo, vol. 4 of |
| Depositing User: | Briony Heyhoe |
| Date Deposited: | 13 Jul 2007 |
| Last Modified: | 28 Jul 2010 19:20 |
| URI: | http://eprints.hud.ac.uk/id/eprint/263 |
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