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Allosteric pitch length tuning of a dinuclear double helicate

Baylies, Christian J., Jeffery, John C., Miller, T.A., Moon, Ryan, Rice, Craig R. and Riis-Johannessen, T. (2005) Allosteric pitch length tuning of a dinuclear double helicate. Chemical Communications. pp. 4158-4160. ISSN 1364-548X

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    Abstract

    Self assembly of the ditopic ligand L1 with Cu2+ gives the dinuclear double helicate [Cu2(L1)2]4+, which can further coordinate s-block cations. This coordination alters the helicate pitch to a variety of different lengths depending on the size and charge of the guest cation.

    Item Type: Article
    Additional Information: UoA 18 (Chemistry) This journal is © The Royal Society of Chemistry 2005
    Subjects: Q Science > QD Chemistry
    Schools: School of Applied Sciences
    School of Applied Sciences > Materials and Catalysis Research Centre
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    References:

    1 J.-M. Lehn, Supramolecular Chemistry, VCH, Weinheim, 1995;
    J. W. Steed and J. L. Atwood, Supramolecular Chemistry, John Wiley
    and Sons, Chichester, 2000; M. J. Hannon and L. J. Childs, Supramol.
    Chem., 2004, 16, 7; M. Albrecht, Chem. Rev., 2001, 101, 3547;
    M. Albrecht, Chem. Soc. Rev., 1998, 27, 281; C. Piguet,
    G. Bernardinelli and G. Hopfgartner, Chem. Rev., 1997, 97, 2005;
    E. C. Constable, in Comprehensive Supramolecular Chemistry;
    Polynuclear Transition Metal Helicates, ed J.-P. Sauvage, Elsevier,
    Oxford, 1996, vol. 9, pp. 213.
    2 E. C. Riesgo,Y.Z.Hu andR.P.Thummel, Inorg. Chem., 2003, 42, 6648.
    3 C. R. Rice, S.Wo¨rl, J. C. Jeffery, R. L. Paul and M. D. Ward, Chem.
    Commun., 2000, 1529; C. R. Rice, S. Wo¨rl, J. C. Jeffery, R. L. Paul and
    M. D. Ward, J. Chem. Soc., Dalton Trans., 2001, 550.
    4 C. J. Baylies, L. P. Harding, J. C. Jeffery, T. Riis-Johannessen and
    C. R. Rice, Angew. Chem. Int. Ed., 2004, 43, 4515.
    5 A. L. Spek, J. Appl. Crystallogr., 2003, 36, 7.

    Depositing User: Briony Heyhoe
    Date Deposited: 13 Jul 2007
    Last Modified: 09 Sep 2010 11:40
    URI: http://eprints.hud.ac.uk/id/eprint/260

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